How to move TempDB to another drive.

Open Query Analyzer and connect to your server. Run this script to get the names of the files used for TempDB.
USE TempDB
GO
EXEC sp_helpfile
GO

Results will be something like:
name fileid filename filegroup size
——- —— ————————————————————– ———- ——-
tempdev 1 C:Program FilesMicrosoft SQL ServerMSSQLdatatempdb.mdf PRIMARY 16000 KB
templog 2 C:Program FilesMicrosoft SQL ServerMSSQLdatatemplog.ldf NULL 1024 KB
along with other information related to the database. The names of the files are usually tempdev and demplog by default. These names will be used in next statement.
=========================================

Run following code, to move mdf and ldf files.

USE master
GO
ALTER DATABASE TempDB MODIFY FILE
(NAME = tempdev, FILENAME = 'd:datatempdb.mdf')
GO
ALTER DATABASE TempDB MODIFY FILE
(NAME = templog, FILENAME = 'e:datatemplog.ldf')
GO

The definition of the TempDB is changed. However, no changes are made to TempDB till SQL Server restarts. Please stop and restart SQL Server and it will create TempDB files in new locations.